SPEC 3.5.1.6 • ELECTRICITY
Electromotive Force and Internal Resistance
Understanding EMF, terminal pd, and energy losses in real power sources
What is EMF?
Electromotive force (EMF) is not actually a force - it's a potential difference measured in volts.
Definition
Electromotive Force (EMF) is the energy transferred per unit charge by a power source.
SymbolQuantityUnit
Electromotive force (EMF)Volts (V)
Energy transferredJoules (J)
ChargeCoulombs (C)
Key Point
EMF represents the total energy the power source can provide to each coulomb of charge.
EMF vs Terminal pd
When a cell is connected to a circuit, the voltage measured across its terminals is less than the EMF.
EMF
The maximum potential difference a cell can provide
Measured when no current flows (open circuit)
Terminal pd
The actual potential difference across the cell terminals
Measured when current flows (closed circuit)
Important
Terminal pd is always less than EMF when current flows, because some energy is dissipated inside the cell itself.
The Relationship
Internal Resistance
All power sources have internal resistance - resistance within the cell itself due to the chemicals and electrodes.
SymbolMeaningUnit
Internal resistance of cellOhms (Ω)
External (load) resistanceOhms (Ω)
The EMF Equation
The EMF of a cell equals the sum of all potential differences around the circuit.
EMF Equation
or equivalently:
IR
Potential difference across external circuit (terminal pd)
Ir
Potential difference "lost" inside the cell
Rearranging
The equation can also be written as:
This shows that terminal pd = EMF minus lost volts
01Worked Example
A cell has EMF 1.5 V and internal resistance 0.50 Ω. It is connected to a 2.5 Ω resistor. Calculate:
(a) the current in the circuit
(b) the terminal pd
(c) the lost volts
a)
Using :
b)
Terminal pd:
c)
Lost volts:
Check: ✓
Lost Volts
The "lost volts" represent energy dissipated as heat inside the cell due to its internal resistance.
Lost Volts
where = lost volts, = current, = internal resistance
Energy Conservation
The EMF provides energy. This energy is split between:
Useful energy delivered to external circuit ()
Wasted energy dissipated in internal resistance ()
Important
Higher current = more lost volts
This is why batteries get warm during heavy use - the internal resistance dissipates energy as heat.
Worked Example02
A battery has EMF 12 V. When connected to an external resistance, a current of 2.0 A flows and the terminal pd is 11 V. Calculate the internal resistance of the battery.
1
Calculate lost volts:
2
Using :
AnswerInternal resistance = 0.50 Ω
Worked Example03
A cell with EMF 1.5 V and internal resistance 0.80 Ω is connected to a lamp of resistance 4.2 Ω. Calculate the power dissipated in the lamp.
1
Calculate current:
2
Power in lamp:
AnswerPower = 0.38 W (2 s.f.)
Circuit Analysis with Internal Resistance
When analysing circuits with internal resistance, treat the internal resistance as a resistor in series with the EMF source.
Total Resistance
The total resistance in the circuit is:where = external resistance, = internal resistance
Problem-Solving Strategy
Find total resistance:
Find current:
Find terminal pd: or
Find lost volts:
Check:
Common Mistake
Don't forget to include the internal resistance when calculating total resistance!
Worked Example04
Two identical cells, each with EMF 1.5 V and internal resistance 0.40 Ω, are connected in series with a 5.2 Ω resistor. Calculate the current and terminal pd across both cells combined.
1
Total EMF (cells in series):
2
Total internal resistance:
3
Current:
4
Terminal pd:
AnswerCurrent = 0.50 A, Terminal pd = 2.6 V
Graphical Analysis
A graph of terminal pd (V) against current (I) gives a straight line that can be used to find EMF and internal resistance.
Linear Form
Comparing with :
Y-Intercept
EMF (ε)
When I = 0, V = ε
Gradient
−r (negative)
Gradient =
Worked Example05
A V-I graph for a cell shows that when I = 0, V = 1.50 V, and when I = 0.40 A, V = 1.30 V. Determine the EMF and internal resistance.
1
EMF = y-intercept = 1.50 V (value of V when I = 0)
2
Gradient =
3
Since gradient = −r: internal resistance r = 0.50 Ω
Answerε = 1.50 V, r = 0.50 Ω
06Worked Example
A student measures the following data for a cell:
I / A0.100.200.300.400.50
V / V1.421.341.261.181.10
Determine the EMF and internal resistance of the cell.
1
Calculate gradient:
2
Internal resistance: r = 0.80 Ω
3
Using :
4
Answerε = 1.50 V, r = 0.80 Ω
Practice
Question 1: A cell has EMF 1.55 V and internal resistance 0.25 Ω. When connected to a resistor, the current is 0.50 A. Calculate (a) the terminal pd, (b) the resistance of the resistor.
a)
Lost volts:
•
Terminal pd:
b)
Answer(a) 1.43 V (b) 2.85 Ω
Practice
Question 2: A battery with EMF 9.0 V and internal resistance 1.5 Ω is connected to a 6.0 Ω resistor. Calculate the power dissipated (a) in the external resistor, (b) in the internal resistance.
1
Current:
a)
Power in external resistor:
b)
Power in internal resistance:
Answer(a) 8.6 W (b) 2.2 W
Summary
Key Equations
EquationDescription
EMF = energy per unit charge
EMF = current × total resistance
Terminal pd = EMF − lost volts
Lost volts = current × internal resistance
Key Exam Skills
Calculate current, terminal pd, and lost volts in circuits with internal resistance
Determine EMF and internal resistance from V-I graphs
Analyse circuits with cells in series
Remember
EMF = maximum pd (no current) | Terminal pd = actual pd (with current) | Lost volts = energy wasted inside cell
Next: What is EMF?